
Technical Bulletin # P-13
Changes In Piping Trends Which
Have
Occurred Over The Past Few Decades

THE PROBLEM:
One of the first comments frequently
expressed by property managers and engineers suddenly faced with a pipe
corrosion problem is that they wouldn't expect to see it at a property of such
young age. A failed section of 45 year old condenser water pipe they might
expect; a similar problem at a 7 year old property or new renovation is almost
beyond belief.
In recent years, ECI has performed
numerous ultrasonic investigations of either very old pipe installed in the
early 1900's, or at properties where a combination of old and new pipe exist.
We have found the test results a remarkable demonstration of how environmental
concerns and government restrictions, combined with cost cutting and less
tolerant engineering practices, have greatly reduced the life expectancy of
most new piping installations.
THE SOLUTION:
Some generalizations regarding some pipe
related changes that have occurred over the past few decades are offered below,
and may help to shed not only some light on the underlying reasons for certain
operating problems, but how to avoid them in the first place.
Pipe Quality
First and foremost is the obvious
superiority in quality and corrosion resistance of pre World War II pipe to
that manufactured today - whether foreign or domestic. Our testing of steam
systems from 1909 have shown a minimal loss of only perhaps 40% from the
original wall thickness. Testing of some galvanized steel domestic water risers
from 1920 have shown little if any wall loss. We have certified 80 year old
steam condensate pipe, which traditionally suffers from the acidic conditions
of condensate requiring frequent replacement, as useful for another 50 years of
service.
Condenser water systems from the early
1940's have been documented to corrode at well below 1 MPY and offer many
decades of future service - even at building locations where chemical treatment
was poor or non-existent.
In contrast, we find few new properties
able to control corrosion to below 5 MPY today without expending extraordinary
cost, monitoring, and physical effort. Chemical treatment programs costing
$10,000 only 15 years ago now reach almost 10 times that expense. Fully
automatic chemical feed and bleed systems are absolutely mandatory. Yet,
ultrasonic and metallurgical testing at new installations has revealed
corrosion rates typically in the 3 - 5 MPY range, with some examples exceeding
15 to 20 MPY even in cases where the chemical water treatment has been
extremely well maintained.
We have either directly seen or have been
advised of condenser water piping systems which have been entirely replaced
after only 10 years in service, and have found large diameter 8 in. and 12 in.
main risers repaired throughout using emergency pipe clamps. The use of copper
in smaller diameter distribution piping has become the standard practice today
in the effort to avoid the effects of corrosion against carbon steel. Larger
diameter 8 in. and 12 in. condenser water piping systems running the height of
buildings have been entirely replaced using extra heavy copper, ceramic or
plastic lined pipe, and even 304 or 314 stainless steel - such extraordinary
expense solely in the effort to avoid the increasingly destructive effects of
corrosion.
Wrought iron pipe, which is well
recognized and documented to provide extremely long life due to its internal
grain structure and inherently high corrosion resistance, can be found at many
older pre-1970 properties. However, it was removed from American production in
1968 and is no longer available. In examples where we have investigated
properties having both new carbon steel and older wrought iron pipe, we have
consistently provided remaining service life estimates in the hundreds of years
for the wrought iron, as opposed to a few decades or less for the newly
installed carbon steel. In many examples, we have found unpainted wrought iron
pipe surviving 50 or more years of outdoor weathering with only a fine layer of
surface rust and the original ASME stamp markings still intact.
While foreign produced pipe from Japan,
Korea, Mexico, South America, and Eastern Europe has traditionally shown the
greatest susceptibility to corrosion, we have not found American produced
carbon steel pipe product of significantly higher quality. Aside from the
obvious net effects of stringent environmental and government over-regulation
and the competition of low cost foreign steel, we have not been able to
establish suitable explanation for the obvious difference in new vs. old
American pipe products.
Other chemical and physical factors exist
beyond the ASME fabrication specification itself - which we believe play a key
role in the corrosion susceptibility or resistance of any carbon steel
pipe.
In addition to pipe quality, other
changing factors acting against steel pipe produced today obviously exist. For
those many reasons, ECI strongly recommends that a higher corrosion rate should
be anticipated regardless of any corrosion control measures planned. It should
be noted that standardized corrosivity tests, laboratory methods capable of
measuring the susceptibility of a metal to a typical corrosive environment and
rating that metal according to an established numerical scale, are available,
and offer an excellent prediction or warning of potential corrosion problems.
Laboratory testing can also verify whether ASTM A53 Grade B labeled pipe is
actually that.
In response to such observed increases in
corrosion, many property managers and engineers have turned to the use of Type
L copper tubing (commonly termed pipe) for all smaller diameter runout
distribution piping, and in some cases even for main risers. This, however, is
only a short term solution to the often more complex problem, and in some cases
may actually complicate an existing corrosion problem with additional and
unseen threats.
Important to consider in the substitution
of copper pipe for carbon steel is the significant difference in initial wall
thickness. Standard Type L copper for 3 in. diameter pipe has a standard wall
thickness of only 0.090 in., whereas 3 in. A 53 Schedule 40 carbon steel has a
wall thickness of 0.216 in. Compared to steel pipe having a stress efficiency
(a strength rating, not pressure rating) of 15,000 lb./in., B 88 copper pipe
only offers 6,000 lb./in. - a physical decrease in strength of 60%! Copper pipe
has less than half the tensile strength of steel, and quickly loses that
strength at higher temperatures.
It is generally recognized that the
minimum acceptable wall thickness for copper pipe under any conditions is 0.049
in. At higher pressures, this minimum value increases - thereby allowing for
little physical wall loss to occur before being judged unsuitable for further
service. Copper pipe, since it exhibits far less physical strength than steel,
will fail sooner than steel at the same wall thickness and under the same
internal pressure - making it obvious that the greatest threat for any copper
components exists at the higher operating pressures.
While the corrosion rate against copper
is commonly believed to exist below 0.5 MPY under all conditions, ECI has well
documented a relationship between high steel and copper corrosion rates. In
fact, once the average corrosion rate against carbon steel exceeds 10 MPY, the
copper corrosion rate will often increase about 10 times its normal value as
well. In many of our previous examinations of condenser water systems which
have shown a high corrosion rate against carbon steel, we have also measured
elevated corrosion attack against copper pipe.
In fact, it is not uncommon to identify
condenser water systems having both a high steel corrosion rate of 15 MPY and a
corrosion rate against copper at 5 MPY or more. Having a 5 MPY copper corrosion
rate aggressively working against piping which may only have an available 30
mils to 40 mils (0.030 in. to 0.040 in.) of wall thickness over minimum
acceptable standards translates to a system which will reach those minimum
standards in only a few years.
Copper therefore should not be relied
upon or viewed as any form of safe or corrosion immune alternative given
conditions where a high corrosion rate has already been established. For those
contemplating the use of copper piping as an alternative to carbon steel, a few
recommendations worthwhile to remember:
- Similar to steel pipe, copper is also
available in extra heavy or Type K grade. This only offers an additional 20% to
30% wall thickness, but may prove worth the extra cost if intended for
installation in an already elevated corrosion environment or at locations
having a higher operating pressure.
- Copper pipe, in the small diameter 1-1/2 in.
to 3 in. sizes typically used to replace steel runout lines, eliminates the
inherent threat in using threaded fittings and the immediate 50% or greater
wall loss caused by the threading process itself. However, the entire weight or
pressure of the system is now focused upon the sweated joint - with no physical
interference such as a thread to secure it in place.
Given sufficient
time, a 95/5 soldered joint can deteriorate in quality and fail.
Dezincification is one commonly recognized problem. A defective solder
connection can produce a similar failure in less time. For any higher pressure
locations, therefore, it is worth the additional expense and time to use
stronger silver solder or braze rather than standard solder.
- The use of copper in a steel piping system
immediately creates the possibility for galvanic corrosion to occur -
dramatically increasing the deterioration of the steel where such metals
directly meet. All connections between dissimilar metals should therefore
always utilize galvanic insulating fittings between them.
- Since copper corrosion is not often
considered a problem, it is not often chemically protected either. Standard
chemical corrosion inhibitors may offer some protection against copper
corrosion rates, but in order to achieve good copper corrosion control, azole
or some other copper specific corrosion inhibitor must be included in the
chemical treatment program.
A chemical analysis of the condenser water
showing the PPM of copper (minus the amount of copper in the make-up water)
multiplied by the estimated volume of water in the entire system, will provide
an indication of the amount of copper which is being lost into the system due
to the effects of corrosion.
System Engineering
For older pre-1970's building properties,
it is unlikely to find anything but Schedule 80 or Extra Heavy black pipe in
use for condenser, steam or steam condensate service. We have even found Extra
strong or Schedule 80 pipe installed for chill water and closed secondary
systems of older properties. However, today, much thinner Schedule 40 has
become standard.
Contrasted to a 0.322 in. wall thickness
for an 8 in. Schedule 40 pipe, Schedule 80 provides a significantly greater
0.500 in. of available steel. For larger diameter Standard pipe of 0.375 in.
wall thickness, Extra Heavy again offers 0.500 in. thickness. With internal
operating pressures rarely a deciding factor on pipe selection within the
commercial building market, the previous use of heavier materials, we believe,
has been more intended to counteract the known effects of corrosion activity
and thereby provide longer service life.
It is important to realize that decades
ago, design engineering for piping systems assumed a reasonable 1 MPY corrosion
rate over an intended life expectancy of about 65 years for the typical
property - therefore a theoretical 65 mil corrosion rate or "corrosion
factor" was normally added into piping calculations for open water
condenser applications. In other words, consulting engineers assumed a total
loss of only 65 mils of pipe over the assumed lifetime of the property. Any
additional pipe wall thickness exceeding the corrosion factor and that needed
to contain the internal pressure and stresses was simply extra insurance
against anticipated corrosion and operating problems.
Today, it is not unusual to measure the
same loss of 65 mils after only 5 to 10 years, sometimes in as few as 3 years
(Many of the sample corrosion photographs on this site are of pipe less than 10
to 15 years old). But while corrosion activity has obviously increased, the
response to the greater loss of pipe has not been applied to the design and
planning of modern piping systems - leaving very little if any physical
tolerance for a system wide corrosion rate exceeding a few mils per year.
This change in engineering design toward
using thinner Schedule 40 pipe, and sometimes Schedule 20, is far more obvious
and threatening in smaller diameter threaded applications - where the
additional loss of metal during the threading process often reduces the life
expectancy of condenser water piping to a decade or less. Threading typically
reduces the available wall thickness by over 50% - leaving a 0.154 in. thick
piece of 2 in. Schedule 40 pipe, less its thread cut of 0.087 in., with a true
available and working wall thickness of only 0.067 in. beginning at day one!
View Tables P-13
A&B for a visual thickness comparison of Schedule 10, 20, 40 and 80
pipe.
For systems having a typical 5 MPY
corrosion rate, total penetration of the threads will occur within 13 years of
installation - guaranteed! In reality, failure usually occurs years earlier. In
fact, the use of Schedule 40 or Standard grade pipe in threaded open water
condenser applications does not even meet minimum acceptable engineering
guidelines for piping systems.
It is worthwhile to simply stress that in
applications where small diameter piping will be installed, the use of Schedule
80 is very highly recommended. Ample technical and engineering documentation
exists to fully support this argument. See Technical Bulletin
# P-02 regarding the danger of using Schedule 40 pipe in threaded
applications.
Water Treatment
For decades, building engineers relied
solely upon the use of chromate based chemical treatments to provide the
required corrosion protection of steel piping systems. With even the most
inferior application methods, often nothing more than an unmeasured scoop of
chromate powder dumped into the cooling tower sump at irregular intervals,
corrosion could be maintained at or below 1 MPY. Biological fouling was a
rarely encountered problem due to chromate's inherent toxicity.
Such trouble free operation ended,
however, in the mid-1980's - with the prohibition of all chromate use in open
water circulating systems. Today, molybdate, phosphate, and other approved
chemical inhibitors rarely equal the effectiveness of chromate treatments.
Though offering impressive corrosion suppression in bench test or laboratory
settings, non-chromate programs rarely provide similar results in the
field.
Through our involvement with ultrasonic
pipe testing, we have identified multiple examples where the highest corrosion
rates have been found exclusively at those areas having the lowest flows. In
addition, non-chromate treatments offer no biological or fungal control -
thereby placing increased emphasis on the use of alternating biocide chemicals.
Yet, biocides themselves have had their effective half-life reduced to about 6
hours by federal and state environmental regulators.
The result - a legal limitation of the
amount of biocide one can apply over a given period of time, as well as a legal
limitation of its strength, effectiveness, and time it will remain active. And
yet, biological activity has been found to play an increasing role in metal
corrosion - MIC being the most serious piping threat known.
The alternative, oxidizing biocides such
as chlorine, bromine and ozone, all offer excellent biological control at the
trade off of increased corrosion and pitting. The common overuse of oxidizing
agents such as chlorine on a weekly basis have been known to produce severe
pitting of metal surfaces, and to quickly remove the galvanizing from cooling
tower pan surfaces. Together, the combination of all the above factors has
placed a high priority on corrosion control which did not exist 20 years ago,
and has raised chemical treatment, and the monitoring of its effectiveness, to
new levels of importance within those involved in building engineering,
maintenance, and operations. Read Technical
Bulletin # M-06 about an extremely effective new biocide.
Free Cooling
Energy costs to cool any large commercial
building are enormous. Extending daily hours and the cooling season, necessary
today for many tenants and especially computer oriented operations, can more
than double that expense.
In the interest of eliminating the high
cost of operating mechanical chillers when outdoor temperatures are low, the
idea of directly routing condenser water through the chilled water piping
appeared in the 1950's and 60's, and was widely accepted. Today, many older
building properties still have what is known as a "Strainercycle" unit.
Patented under the "Strainercycle" cross cooling concept, a high
capacity, automatically backwashing filter was the key component thought to
prevent the dirt, debris, and biological content, always present in an open
water cooling tower system, from entering the closed and generally clean chill
water and secondary piping.
Thirty to forty years later, property
owners and operators are learning that the standard 110 micron particle
retention of the filter was not quite sufficient to eliminate the type of
piping damage one typically finds in condenser water systems. Particle
distribution studies generally find the majority of suspended condenser water
particulates down in the 40 to 50 micron range. And of course, only a
sub-micron filter would be capable of removing microbiological contamination -
a known major factor influencing pipe corrosion.
Ultrasonic wall thickness and
metallurgical testing of building properties currently or previously operating
cross cooling systems have very well documented similarly higher condenser
water corrosion rates and deep pitting throughout their associated closed
cooling systems. Unlike condenser water piping, which is generally of large
diameter welded piping throughout and, in older properties, often constructed
of extra heavy material, closed systems distribute down to small size piping,
and ultimately to even smaller cooling coils.
Furthermore, closed systems are
traditionally constructed of standard or Schedule 40 piping which provides less
available wall thickness, and have threaded connections further limiting
available wall thickness. Dirt, particulates, iron oxide corrosion products,
and microbiological contamination entering through the cooling tower, or
originating in the condenser water piping, typically pass through a 110 micron
screen filtering element and enter the closed system. There, the contamination
migrates downward and under a continually lower flow velocity where it
eventually settles out and remains.
While the majority of foreign material
does escape again through the cooling tower blowdown, the amount which remains
can create substantial secondary problems - most noticeably a loss of cooling
or heating efficiency across the fan's coils. As a result, many property owners
and operators have replaced their cross cooling filtration with fully isolating
plate and frame heat exchangers.
ECI strongly recommends that properties
having once operated as a free cooling system should view their closed systems
with the same degree of concern as they would a condenser water system. Due to
the large volume of debris and corrosion product likely trapped within a free
cooling closed system, we strongly recommend the installation of side stream
filtration and additional chemical dispersants in order to gradually resuspend
and remove those deposits - thereby reducing under deposit corrosion,
decreasing corrosion rates, and extending the life of the piping system.
See Technical Bulletin
# W-01 regarding the benefits of side stream filtration for closed piping
systems.



